Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis book
Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis book
Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis.cCorinna Reisinger
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Author: Corinna Reisinger
Number of Pages: 276 pages
Published Date: 18 Jul 2014
Publisher: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Publication Country: Berlin, Germany
Language: English
Format: PDF
ISBN: 9783642435331
File size: 37 Mb
Download Link: Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones An Approach Through Asymmetric Organocatalysis
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Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic alpha,beta-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro-peroxi-dation of alpha,beta-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.
Read online Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis Buy Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis Download Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis for pc, mac, kindle, readers Download to iPad/iPhone/iOS, B&N nook Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis
Oscar Romero and the Communion of Saints : A Biography download PDF, EPUB, Kindle
Le Correspondant, Volume 97... download PDF, EPUB, Kindle
Bulletin of the Scientific Laboratories of Denison University, Volume 11... pdf
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Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis.cCorinna Reisinger
Author: Corinna Reisinger
Number of Pages: 276 pages
Published Date: 18 Jul 2014
Publisher: Springer-Verlag Berlin and Heidelberg GmbH & Co. KG
Publication Country: Berlin, Germany
Language: English
Format: PDF
ISBN: 9783642435331
File size: 37 Mb
Download Link: Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones An Approach Through Asymmetric Organocatalysis
---------------------------------------------------------------
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic alpha,beta-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro-peroxi-dation of alpha,beta-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.
Read online Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis Buy Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis Download Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis for pc, mac, kindle, readers Download to iPad/iPhone/iOS, B&N nook Epoxidations and Hydroperoxidations of Alpha,SS-Unsaturated Ketones : An Approach Through Asymmetric Organocatalysis
Oscar Romero and the Communion of Saints : A Biography download PDF, EPUB, Kindle
Le Correspondant, Volume 97... download PDF, EPUB, Kindle
Bulletin of the Scientific Laboratories of Denison University, Volume 11... pdf
Download book Metodika Rassledovaniya I Sudebnogo Razbiratel'stva Ubiystv
Dinero y Conciencia : A Quien Sirve Mi Dinero? download book
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mass effect 3 leviathan achievements conspiracy theories